Syntheses, Characterization, and Properties of Three-Dimensional Pillared Frameworks with Entanglement
Identifieur interne : 000700 ( Chine/Analysis ); précédent : 000699; suivant : 000701Syntheses, Characterization, and Properties of Three-Dimensional Pillared Frameworks with Entanglement
Auteurs : RBID : Pascal:11-0215855Descripteurs français
- Pascal (Inist)
- Structure à pilier, Polymère coordination, Structure cristalline, Structure moléculaire, Cadmium, Diacide carboxylique, Acide propionique, Synthèse hydrothermale, Carboxylate, Ligand, Photoluminescence, Propriété thermique, Stabilité thermique, Dépendance température, Sulfure d'indium, Agrégat métallique, Susceptibilité magnétique, Mesure magnétique, Ferromagnétique, 6166, 7855, 6540D, 7550C.
- Wicri :
- concept : Cadmium.
English descriptors
- KwdEn :
- Cadmium, Carboxylates, Crystal structure, Dicarboxylic acids, Ferromagnetic materials, Hydrothermal synthesis, Indium sulfide, Ligands, Magnetic measurement, Magnetic susceptibility, Metal clusters, Molecular structure, Photoluminescence, Pillared structure, Polychelate, Propionic acid, Temperature dependence, Thermal properties, Thermal stability.
Abstract
Six new coordination polymers, namely, [Cd3(L)2(dpa)2(H2O)] (1), [Co3(L)2(dpa)2(H2O)2].H2O (2), [Cd(L)(chda)0.5] (3), [Cd(L)(dc)0.5-(H2O)] (4), [Cd2(L)2(cca)].2H2O (5), and [Cd2(L)2(cppa)].2H2O (6) [HL = 3,5-di(imidazol-1-yl)benzoic add, H2dpa = diphenic add, H2chda = 1,4cydohexane-dicarboxylic acid, H2dc = = 1,4-benzenediactylic acid, H2cca = 4-carboxycinnnnamic acid, H2cppa = 3-(4-carboxyphenyl)propionic acid] have been obtained under hydrothermal conditions. Complexes 1 and 2 are novel (3,6)-connected three-dimensional (3D) frameworks based on trinuclear subunits. Complex 3 shows a rare 4-fold interpenetrating 3D dmc net, and 4 features a uninodal 6-connected 3D self-penetrating framework Both 5 and 6 possess unusual 3-fold interpenetrating 3D (3,4)-connected InS nets. In 1-6 each metal atom is coordinated by the combination of L and auxiliary carboxylate ligands. In 1 and 2 the auxiliary carboxylate ligand plays an important role in the formation of metal cluster based subunits. In 3-6 the auxiliary carboxylate ligands pillar the metal - L- two-dimensional networks to form entangled 3D frameworks. Furthermore, the photoluminescence and thermal stabilities of complexes 1-6 were investigated. The temperature-dependent magnetic susceptibility measurements of compound 2 show the ferromagnetic interactions between the metal centers mediated through the μ-O and/or O-C-O linkages.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Syntheses, Characterization, and Properties of Three-Dimensional Pillared Frameworks with Entanglement</title><author><name>ZHI SU</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University</s1><s2>Nanjing 210093</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>République populaire de Chine</country><wicri:noRegion>Nanjing 210093</wicri:noRegion></affiliation></author><author><name>JIAN FAN</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University</s1><s2>Nanjing 210093</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>République populaire de Chine</country><wicri:noRegion>Nanjing 210093</wicri:noRegion></affiliation></author><author><name>MIN CHEN</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University</s1><s2>Nanjing 210093</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>République populaire de Chine</country><wicri:noRegion>Nanjing 210093</wicri:noRegion></affiliation></author><author><name sortKey="Okamura, Taka Aki" uniqKey="Okamura T">Taka-Aki Okamura</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Macromolecular Science, Graduate School of Science, Osaka University</s1><s2>Toyonaka, Osaka 560-0043</s2><s3>JPN</s3><sZ>4 aut.</sZ></inist:fA14><country>Japon</country><wicri:noRegion>Toyonaka, Osaka 560-0043</wicri:noRegion></affiliation></author><author><name sortKey="Sun, Wei Yin" uniqKey="Sun W">Wei-Yin Sun</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University</s1><s2>Nanjing 210093</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>République populaire de Chine</country><wicri:noRegion>Nanjing 210093</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">11-0215855</idno><date when="2011">2011</date><idno type="stanalyst">PASCAL 11-0215855 INIST</idno><idno type="RBID">Pascal:11-0215855</idno><idno type="wicri:Area/Main/Corpus">003238</idno><idno type="wicri:Area/Main/Repository">002429</idno><idno type="wicri:Area/Chine/Extraction">000700</idno></publicationStmt><seriesStmt><idno type="ISSN">1528-7483</idno><title level="j" type="abbreviated">Cryst. growth des.</title><title level="j" type="main">Crystal growth & design</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cadmium</term><term>Carboxylates</term><term>Crystal structure</term><term>Dicarboxylic acids</term><term>Ferromagnetic materials</term><term>Hydrothermal synthesis</term><term>Indium sulfide</term><term>Ligands</term><term>Magnetic measurement</term><term>Magnetic susceptibility</term><term>Metal clusters</term><term>Molecular structure</term><term>Photoluminescence</term><term>Pillared structure</term><term>Polychelate</term><term>Propionic acid</term><term>Temperature dependence</term><term>Thermal properties</term><term>Thermal stability</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Structure à pilier</term><term>Polymère coordination</term><term>Structure cristalline</term><term>Structure moléculaire</term><term>Cadmium</term><term>Diacide carboxylique</term><term>Acide propionique</term><term>Synthèse hydrothermale</term><term>Carboxylate</term><term>Ligand</term><term>Photoluminescence</term><term>Propriété thermique</term><term>Stabilité thermique</term><term>Dépendance température</term><term>Sulfure d'indium</term><term>Agrégat métallique</term><term>Susceptibilité magnétique</term><term>Mesure magnétique</term><term>Ferromagnétique</term><term>6166</term><term>7855</term><term>6540D</term><term>7550C</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Cadmium</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Six new coordination polymers, namely, [Cd<sub>3</sub>(L)<sub>2</sub>(dpa)<sub>2</sub>(H<sub>2</sub>O)] (1), [Co<sub>3</sub>(L)<sub>2</sub>(dpa)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>].H<sub>2</sub>O (2), [Cd(L)(chda)<sub>0.5</sub>] (3), [Cd(L)(dc)<sub>0.5</sub>-(H<sub>2</sub>O)] (4), [Cd<sub>2</sub>(L)<sub>2</sub>(cca)].2H<sub>2</sub>O (5), and [Cd<sub>2</sub>(L)<sub>2</sub>(cppa)].2H<sub>2</sub>O (6) [HL = 3,5-di(imidazol-1-yl)benzoic add, H<sub>2</sub>dpa = diphenic add, H<sub>2</sub>chda = 1,4cydohexane-dicarboxylic acid, H<sub>2</sub>dc = = 1,4-benzenediactylic acid, H<sub>2</sub>cca = 4-carboxycinnnnamic acid, H<sub>2</sub>cppa = 3-(<sub>4</sub>-carboxyphenyl)propionic acid] have been obtained under hydrothermal conditions. Complexes 1 and 2 are novel (3,6)-connected three-dimensional (3D) frameworks based on trinuclear subunits. Complex 3 shows a rare 4-fold interpenetrating 3D dmc net, and 4 features a uninodal 6-connected 3D self-penetrating framework Both 5 and 6 possess unusual 3-fold interpenetrating 3D (3,4)-connected InS nets. In 1-6 each metal atom is coordinated by the combination of L and auxiliary carboxylate ligands. In 1 and 2 the auxiliary carboxylate ligand plays an important role in the formation of metal cluster based subunits. In 3-6 the auxiliary carboxylate ligands pillar the metal - L<sup>-</sup> two-dimensional networks to form entangled 3D frameworks. Furthermore, the photoluminescence and thermal stabilities of complexes 1-6 were investigated. The temperature-dependent magnetic susceptibility measurements of compound 2 show the ferromagnetic interactions between the metal centers mediated through the μ-O and/or O-C-O linkages.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1528-7483</s0></fA01><fA03 i2="1"><s0>Cryst. growth des.</s0></fA03><fA05><s2>11</s2></fA05><fA06><s2>4</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Syntheses, Characterization, and Properties of Three-Dimensional Pillared Frameworks with Entanglement</s1></fA08><fA11 i1="01" i2="1"><s1>ZHI SU</s1></fA11><fA11 i1="02" i2="1"><s1>JIAN FAN</s1></fA11><fA11 i1="03" i2="1"><s1>MIN CHEN</s1></fA11><fA11 i1="04" i2="1"><s1>OKAMURA (Taka-Aki)</s1></fA11><fA11 i1="05" i2="1"><s1>SUN (Wei-Yin)</s1></fA11><fA14 i1="01"><s1>Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University</s1><s2>Nanjing 210093</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>5 aut.</sZ></fA14><fA14 i1="02"><s1>Department of Macromolecular Science, Graduate School of Science, Osaka University</s1><s2>Toyonaka, Osaka 560-0043</s2><s3>JPN</s3><sZ>4 aut.</sZ></fA14><fA20><s1>1159-1169</s1></fA20><fA21><s1>2011</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>27261</s2><s5>354000192040080420</s5></fA43><fA44><s0>0000</s0><s1>© 2011 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>30 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>11-0215855</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Crystal growth & design</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>Six new coordination polymers, namely, [Cd<sub>3</sub>(L)<sub>2</sub>(dpa)<sub>2</sub>(H<sub>2</sub>O)] (1), [Co<sub>3</sub>(L)<sub>2</sub>(dpa)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>].H<sub>2</sub>O (2), [Cd(L)(chda)<sub>0.5</sub>] (3), [Cd(L)(dc)<sub>0.5</sub>-(H<sub>2</sub>O)] (4), [Cd<sub>2</sub>(L)<sub>2</sub>(cca)].2H<sub>2</sub>O (5), and [Cd<sub>2</sub>(L)<sub>2</sub>(cppa)].2H<sub>2</sub>O (6) [HL = 3,5-di(imidazol-1-yl)benzoic add, H<sub>2</sub>dpa = diphenic add, H<sub>2</sub>chda = 1,4cydohexane-dicarboxylic acid, H<sub>2</sub>dc = = 1,4-benzenediactylic acid, H<sub>2</sub>cca = 4-carboxycinnnnamic acid, H<sub>2</sub>cppa = 3-(<sub>4</sub>-carboxyphenyl)propionic acid] have been obtained under hydrothermal conditions. Complexes 1 and 2 are novel (3,6)-connected three-dimensional (3D) frameworks based on trinuclear subunits. Complex 3 shows a rare 4-fold interpenetrating 3D dmc net, and 4 features a uninodal 6-connected 3D self-penetrating framework Both 5 and 6 possess unusual 3-fold interpenetrating 3D (3,4)-connected InS nets. In 1-6 each metal atom is coordinated by the combination of L and auxiliary carboxylate ligands. In 1 and 2 the auxiliary carboxylate ligand plays an important role in the formation of metal cluster based subunits. In 3-6 the auxiliary carboxylate ligands pillar the metal - L<sup>-</sup> two-dimensional networks to form entangled 3D frameworks. Furthermore, the photoluminescence and thermal stabilities of complexes 1-6 were investigated. The temperature-dependent magnetic susceptibility measurements of compound 2 show the ferromagnetic interactions between the metal centers mediated through the μ-O and/or O-C-O linkages.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60A66</s0></fC02><fC02 i1="02" i2="3"><s0>001B70H55</s0></fC02><fC02 i1="03" i2="3"><s0>001B60E40D</s0></fC02><fC02 i1="04" i2="3"><s0>001B70E50C</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Structure à pilier</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Pillared structure</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Estructura con pilares</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Polymère coordination</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Polychelate</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Polímero coordinación</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Structure moléculaire</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Molecular structure</s0><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Cadmium</s0><s2>NC</s2><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Cadmium</s0><s2>NC</s2><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Diacide carboxylique</s0><s5>06</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Dicarboxylic acids</s0><s5>06</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Acide propionique</s0><s2>NK</s2><s5>07</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Propionic acid</s0><s2>NK</s2><s5>07</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Synthèse hydrothermale</s0><s5>08</s5></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Hydrothermal synthesis</s0><s5>08</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Carboxylate</s0><s5>09</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Carboxylates</s0><s5>09</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Ligand</s0><s5>10</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Ligands</s0><s5>10</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Photoluminescence</s0><s5>11</s5></fC03><fC03 i1="11" i2="3" l="ENG"><s0>Photoluminescence</s0><s5>11</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Propriété thermique</s0><s5>12</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Thermal properties</s0><s5>12</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>Stabilité thermique</s0><s5>13</s5></fC03><fC03 i1="13" i2="3" l="ENG"><s0>Thermal stability</s0><s5>13</s5></fC03><fC03 i1="14" i2="3" l="FRE"><s0>Dépendance température</s0><s5>14</s5></fC03><fC03 i1="14" i2="3" l="ENG"><s0>Temperature dependence</s0><s5>14</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Sulfure d'indium</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Indium sulfide</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Indio sulfuro</s0><s5>15</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>Agrégat métallique</s0><s5>16</s5></fC03><fC03 i1="16" i2="3" l="ENG"><s0>Metal clusters</s0><s5>16</s5></fC03><fC03 i1="17" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0><s5>29</s5></fC03><fC03 i1="17" i2="3" l="ENG"><s0>Magnetic susceptibility</s0><s5>29</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Mesure magnétique</s0><s5>30</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Magnetic measurement</s0><s5>30</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Medida magnética</s0><s5>30</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Ferromagnétique</s0><s5>31</s5></fC03><fC03 i1="19" i2="X" l="ENG"><s0>Ferromagnetic materials</s0><s5>31</s5></fC03><fC03 i1="19" i2="X" l="SPA"><s0>Material ferromagnético</s0><s5>31</s5></fC03><fC03 i1="20" i2="3" l="FRE"><s0>6166</s0><s4>INC</s4><s5>71</s5></fC03><fC03 i1="21" i2="3" l="FRE"><s0>7855</s0><s4>INC</s4><s5>72</s5></fC03><fC03 i1="22" i2="3" l="FRE"><s0>6540D</s0><s4>INC</s4><s5>73</s5></fC03><fC03 i1="23" i2="3" l="FRE"><s0>7550C</s0><s4>INC</s4><s5>74</s5></fC03><fN21><s1>143</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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